Equilibrium space charge distribution in a quadrupole ion trap
نویسندگان
چکیده
منابع مشابه
Quadrupole ion trap mass spectrometry.
A number of other features of ITMS systems that will enhance their ability to analyze biological macromolecules are worth mentioning. As has already been demonstrated for ESI/quadrupole, ESI/magnetic sector, and ESI/FTICR systems, the capability of inducing fragmentation of the ESI-generated multiply charged ions of biological macromolecules in the capillary/skimmer region of the ESI source and...
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We describe a prototype tandem mass spectrometer that is designed to increase the efficiency of linked-scan analyses by >100-fold over conventional linked-scan instruments. The key element of the mass spectrometer is a novel high ion capacity ion trap, combined in tandem configuration with a quadrupole collision cell and a quadrupole mass analyzer (i.e. a TrapqQ configuration). This ion trap ca...
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It has been empirically observed in both experiments and particle-in-cell simulations that space-charge-dominated beams suffer strong growth in statistical phasespace area (degraded quality) and particle losses in alternating gradient quadrupole transport channels when the undepressed phase advance σ0 increases beyond about 85 per lattice period. Although this criterion has been used extensivel...
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Quadrupole ion traps are reviewed, emphasizing recent developments, especially the investigation of new geometries, guided by multiple particle simulations such as the ITSIM program. These geometries include linear ion traps (LITs) and the simplified rectilinear ion trap (RIT). Various methods of fabrication are described, including the use of rapid prototyping apparatus (RPA), in which 3D obje...
متن کاملAn Introduction to Quadrupole Ion Trap Mass Spectrometry
A concise introduction is presented to the theory and application of quadrupole ion trap mass spectrometry. The presentation of the theoretical treatment is based on a demonstration of the equivalence of the force acting on an ion in a quadrupole Ðeld and the force derived from the Mathieu equation ; this equivalence permits the application of the solutions of MathieuÏs equation to the conÐneme...
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ژورنال
عنوان ژورنال: Journal of the American Society for Mass Spectrometry
سال: 1994
ISSN: 1044-0305,1879-1123
DOI: 10.1016/1044-0305(94)85038-0